Chemistry Articles

By: David Bradley

                

Reactive ReportsReactive Reports is a joint venture between ACD/Labs and David Bradley, which New Scientist magazine described as, "A chemistry webzine that is attractively put together and takes a pride in being cutting edge." Reactive Reports was also winner in the 2003 Scientific American Sci-Tech awards. Read our fiftieth "anniversary" announcement in David's science blog. Click here to read the latest issue of Reactive Reports and visit this page for the chemistry webzine archives.

ISSUE 70 - December 2007

Now online featuring an interview with Chinese chemist Weixiang "Andrew" Sun of the College of Material Science & Engineering, at South China University of Technology, Guangzhou, PR China.

ISSUE 70 - November 2007
  • Cats Don't Work Like That
    The three-way catalytic converter in your car does not, it turns out, work the way chemists thought it did. One of the key functions of a "cat" is to convert toxic carbon monoxide into carbon dioxide.
     
  • Double Vision With Coordination Polymers
    Calcite crystals can make you see double. You don't ingest them to achieve some kind of mind warp effect; they are simply birefringent, having essentially two focal points.
     
  • Organic Uranium
    The first ever uranium methylidyne molecule has been synthesized by US chemists despite the reactivity of the heavy, heavy metal.
     
  • Barking Up the Right Tree for Fresh Breath
    A traditional Chinese extract from the bark of the magnolia tree could give you fresh breath and kill off the oral microbes that cause halitosis.
     
ISSUE 69 - October 2007
  • How Cannabis Works
    Why does cannabis get a person "high"? What is it about the psychoactive component in marijuana, THC, or tetrahydrocannabinol, that exerts its special effects?
     
  • An Economical Hydrogen Economy
    If the hyperbole is to be believed, hydrogen gas will be one of the most important fuels of the future.
     
  • The Venusian Greenhouse
    A rare form of carbon dioxide in which one oxygen atom contains ten neutrons instead of the usual eight could be to blame for the searing greenhouse effect on the planet Venus.
     
  • Chocoholics Anonymous
    It probably will not come as a surprise that scientific research funded by chocolate makers Nestle' has demonstrated a link between our love of chocolate and a specific chemical signature programmed into our metabolism.

 

ISSUE 68 - September 2007
  • Fire Resistant Paint
    A way to toughen up the latex particles used to make emulsion paints has been developed by UK chemists.
     
  • Light Controlled Magic Bullet
    Targeting diseased tissue directly with the drug to teach it, the so-called magic bullet, came a step closer thanks to work by Senior Lecturer in Pharmaceutics Colin McCoy of Queen's University Belfast and his colleagues.
     
  • Insecticidal Synthesis
    Professor Steven Ley of Cambridge University and his colleagues over the last two decades have been on a chemical odyssey.
     
  • Plain or Vanilla
    Some men smell of vanilla while others smell of urine, but it is not always down to personal hygiene or ice-cream tainted Cologne.
     

ISSUE #67 July-August 2007
Articles
  • Attractive Changing Colors
    Yadong Yin and colleagues at the University of California, Riverside, have discovered that a simple magnet can be used to change the color of nanoparticles of iron oxide in aqueous suspension.
     
  • Fairytale Insulin Substitute
    People with type I diabetes could one day be prescribed an extract from pumpkins that will drastically cut their reliance on daily insulin injections.
     
  • Multichannel Microchemical Factory
    In the mid-nineties, microchemistry was set to revolutionize the chemical industry.
     
  • No Munchies with Cannabinoid Antagonist
    The pharmaceutical rimonabant latches on to the cannabinoid 1 (CB1) receptors in the brain and blocks their activity.
     
  • Contaminated Seabirds
    A new approach to monitoring seabirds for contamination with polychlorinated biphenyls (PCBs) and other persistent organic pollutants (POPs) has been developed by scientists in Japan.

ISSUE #66 June 2007
Articles
  • Bonding Solution
    The formation of molecular bonds between carbon atoms is fundamental to life on earth as well as the manufacture of countless products on which civilization depends from selective agrochemicals to potent pharmaceuticals and from polymers and plastics to the synthesis of the components of nanotechnology.
     
  • Lengthy Nanobelts
    Think of nanotechnology and the first thing that strikes you is the amazingly small sizes involved.
     
  • Fluorescent Font
    Making and writing with "invisible" ink was always a fascinating wet Saturday afternoon for us as kids.
     
Interviews
  • Mitch André Garcia
    Garcia obtained his BS from the University of California, Riverside, in 2003 in Pure and Applied Chemistry, and then moved to Berkeley to study for his PhD.

ISSUE #65 May 2007
Articles
  • Meeting of Molecular Movie Stars
    A clandestine meeting between molecules, a chemical handshake, and an exchange of energy have all been recorded on camera by scientists in the UK and Germany.
     
  • The Long and the Short of It
    A new composite material that acts as a catalyst to speed up chemical reactions has been developed to create arrays of the world's longest carbon nanotubes.
     
  • A Scent for Explosives
    A new type of biosensor based on yeast, jellyfish proteins, and a rat's sense of smell could sniff out explosives, landmines, and agents, such as sarin gas, according to researchers at Temple University.
     
  • Windows Cause Pollution
    This is not another terrible advertisement for an alternative computer operating system to the eponymous installation mentioned in the title, but an environmental analysis that reveals how dirty windows are a major contributor to urban pollution.

ISSUE #64 April 2007
Articles
  • Proteins' Web of Intrigue
    The latent strength of Miss Muffet's arachnoid friend may have been in sexual allegory, but the image of a spider's web as somehow weak, a glistening, gossamer netting for trapping only flies could not be further from the truth.
     
  • Stem to Sperm
    Stem cells from human bone marrow can be converted into early-stage sperm, according to a research team based at the North-east England Stem Cell Institute (NESCI), Newcastle.
     
  • Dino Remains
    We have not quite entered Jurassic Park, but researchers have successfully extracted protein from a 68 million year old Tyrannosaurus rex bone.
Interviews

ISSUE #63 March 2007
Articles
  • Cocoa Has Beans
    A natural compound found in cocoa, teas, wine, and some fruit and vegetables could lead to a breakthrough in health and nutrition, according to US researchers.
     
  • Chemists Go Round the Bend
    Chemists often think of molecular wires as "shape-persistent" rods with limited flexibility, so says Oxford University's Harry Anderson, and he should know, having worked with the inflexible nanoscopic objects known as molecules since the early 1990s.
     
  • Natural Copy Cat
    Green plants can extract carbon dioxide gas from the air and turn it into sugar molecules using sunlight and give off oxygen.
     
  • Waste Not, Want Not
    A fungus that can convert waste paper into an antibacterial and super-absorbent material has been discovered by researchers at Borĺs University College in Sweden.

ISSUE #62 February 2007
Articles Interviews
  • RCS Publishing Embraces the Semantic Web
    Robert Parker, Managing Director of RSC Publishing discusses a new approach to the publication of scientific papers, and how it will benefit readers and the scientific community at large.

 

Below is an archive of posts up to Issue 61 December 2006

 
Dick Wife Interview with Dick Wife  British-born Richard "Dick" Lewin Wife followed a traditional educational path, receiving his chemistry first degree from the University of Leeds in 1969 and staying on to do an organic PhD with David W. Jones. Read more...
 
  Molecular Light Switch  According to Nobel laureate Roald Hoffmann, "Nanotechnology is the result of the marriage of the synthetic talent of Chemists with a device-driven ingenuity."
 
  Blood, Light, and Water Two molecules that occur naturally in blood have been engineered by scientists from the UK and Japan to use sunlight to split water into hydrogen and oxygen.
 
  Plastic Shape Shifter  Temperature-controlled "triple-shaped plastics" that can change shape from one form to another, then another, have been developed by researchers in Germany and the US.
 
  Bedwetting Chemistry  A higher concentration of sodium and urea in urine could underlie a type of bedwetting in children that does not respond to the common medication, desmopressin.
 
  Rubber Suits You Sir  Military personnel, chemical workers, and others could benefit from a new synthetic rubber material tailored with liquid crystals.
 
  Biomolecules Out on a Wing  Photonic crystals give butterflies their beautiful colors and synthetic versions are now being developed for a range of technological applications.

Issue 60 November 2006

 
Amilra Prasanna "AP" de Silva Interview with Mark Leach
Mark Leach is a chemical researcher with a difference. He has worked at universities in the UK and overseas, acted as an A-level examiner as well as consulting for international companies and organizations. Read more...
 
  Networking Neural Nanotubes  The Internet is a series of tubes...no, sorry...wrong story. Carbon nanotubes are the new material of choice for a wide range of applications.
 
  Fried Rust Could Prevent Arsenic Poisoning A subject that we have returned to on several occasions, arsenic-contaminated drinking water, could one day become a thing of the past thanks to the unexpected discovery of the magnetic properties of rusty nanoparticles.
 
  Large-scale Chemistry Reveals Galactic Origins  Determining the chemical composition of 2000 stars in four of our neighboring dwarf galaxies, is a task even the biggest parallel analytical operation would probably baulk at taking on, although the fees would be enormous.

 

Issue 59 October 2006

 
Amilra Prasanna "AP" de Silva Interview with Amilra Prasanna "AP" de Silva
Amilra Prasanna "AP" de Silva was born on April 29, 1952, in Colombo, Sri Lanka, and obtained his PhD in Organic Photochemistry at Queen's University of Belfast, in 1980, having graduated from the University of Sri Lanka in 1975. Read more...
 
  RNA Chemistry Zips Up Nobel Prize  If Watson and Crick unlocked the mystery of DNA's structure, then Stanford University's Roger Kornberg and his team unzipped the secret of how the cell converts DNA into the RNA needed to make proteins.
 
  Let it Bleed. Not! An international research team has shown that a biocompatible liquid can stop bleeding within seconds. The discovery could cut to the heart of many problems facing hospital emergency rooms and operating theaters.
 
  Drink Up! Lest We Forget  There is potentially good news for red wine lovers whose favorite tipple is Cabernet Sauvignon.

 

Issue 58 September 2006

   Peter LoewInterview with Peter Loew
Peter Loew was born and grew up in Munich, Germany. He gained a degree in chemistry in 1979 and received his PhD in Organic Chemistry in 1983 from the Ludwig-Maximilian University in Munich. From 1983–1986 he took a Post Doc position at the Technical University in Munich in Computer-Chemistry, which was sponsored by ICI Organics Division, UK. Read more...

 

 
  ID Tags for Teenage Molecules  It has been thirteen years since Prasanna "AP" de Silva and his colleagues at Queen's University Belfast published their first paper in the international science journal Nature, outlining how they hoped to convert small molecules into the kind of logical units that could carry out computations.
 
  Drug Discovery at a Snail's Pace
Researchers in the US have isolated a toxin from the venomous cone snail, which lives in the sea.
 
  Anthrax Detector  Researchers in Switzerland have developed a detector for anthrax spores based on a monoclonal antibody that recognizes a specific sugar on the bacterium.

 

Issue 57 - July-August 2006

Andrew Lemon Interview with Andrew Lemon
Lemon was born, and still lives, in the South Hampshire area of Southern England. He gained a first class degree in chemistry with computer science from Reading University and a PhD in Computational Chemistry from the University of Bath on 'Modeling the biological membrane'. Read more...

 
  Smart Materials Self Repair  Dumb materials succumb to rust, but smart materials might be able to heal themselves, thanks to researchers in Europe.
 
  Brush Daily with Cranberries  Cranberries have a special place in modern herbal folklore, the presence of antioxidant flavonoids in these tart but edible berries are thought to have antimicrobial activity.
 
  Grape Expectations  Certain Italian grape varieties used in popular red wines may contain high levels of the sleep hormone melatonin, according to an analysis by Marcello Iriti, Mara Rossoni, and Franco Faoro at the University of Milan. s
 
  PEPping Up the Celiac Diet  An enzyme added to foods containing gluten could put an end to the misery of celiac disease for many sufferers, allowing them to eat almost anything they fancy without having to worry about the effects on their digestive system.
 
  Sweet Solution to Energy Problem  A new process for converting sugar into diesel fuel and feedstock chemicals for the manufacture of plastics, drugs, and other products, could help industry circumvent the problem of rising oil and natural gas prices.
 
  A Spoonful of Slime Helps the Medicine Go Down
The slime that covers the flat-fish plaice contains an antimicrobial agent that kills Staphylococcus aureus, the bacteria causing concern in hospitals across the globe as its drug-resistant strains spread.
 
 

 

Issue 56 - June 2006

William James Griffiths Interview with William James Griffiths
William James Griffiths graduated from Imperial College London in 2004 in Chemistry with Management, he spent several months as a scientist at UK biotech company Celltech, but realized that life behind the bench was not for him and has since invested his time in developing the ChemRefer.com website. Read more...

 
  The Weighty Issue of Fat  Butter lovers everywhere will be pleased to learn that there is yet another reason to abandon margarine in favor of their dairy-derived spread.
 
  A Basic Approach to Chemotherapy  The elusive magic bullet of cancer chemotherapy may be nothing more than a false hope, but now chemists at the University of Kansas have found a way to attack malignant cells with an anticancer drug, while sparing healthy cells.
 
  NASA Lights Fuse on Planetary Carbon Debate
NASA's FUSE (Far Ultraviolet Spectroscopic Explorer) has discovered enormous amounts of carbon gas in a dusty disk surrounding a young star named Beta Pictoris.
 
 

 

Issue 55 - May 2006

Wendy WarrInterview with Wendy Warr
Dr. Wendy Warr has Masters and Doctors degrees in Chemistry from the University of Oxford, England. She is a Chartered Chemist, a Fellow of the Royal Society of Chemistry, and a Fellow of the Chartered Institute of Library and Information Professionals. Read more...

Testing the Byproducts of Cell Death  A new approach to testing whether a particular chemotherapy agent is working well in treating a patient's cancer is being developed by UK scientists.

 

  You Want Benzene With That Soda?
A chemical health story that has been bubbling for several years came to a head earlier this year, as consumers learned that their soft drinks could be contaminated with levels of benzene far higher than national and international drinking water standards allow.

  Da-Da-Da-Der-Dah-Duh-Dah-Daah! Tequila!  Whether celebrating Cinco de Mayo or just having another relaxing day in Margaritaville, a new chemical test could be the assurance you need that the bottle you're downing is genuine tequila.

 

Issue 54 - April 2006

Martin WalkerInterview with Martin Walker
Martin Walker grew up in Whitley Bay on the North East coast of England. In 1981 he received a BSc (Hons) degree in chemistry from the University of Bristol. After graduation he went to work for Fine Organics, Ltd., in the north east of England, where he worked in R&D, developing manufacturing processes for fine chemicals (pharmaceutical intermediates, etc.). Read more...

 

Hula-Hoop DNA Amplification  Periodic nanostructures made of gold nanoparticles and long DNA strands with repeated sequences have been prepared by Michael Brook, Yingfu Li, and colleagues at McMaster University, in Hamilton, Canada. Their approach exploits a technique for duplicating DNA known as "rolling circle amplification" or the "hula-hoop" technique.



Metals Take on Carbon's Bonding Characteristics  A rethink about chemical bonding might be in the cards thanks to research that shows that the metal indium forms bonds in a manner not dissimilar to organic carbon atoms. Extended, or catenated, chains of atoms are common in carbon compounds, but UK chemists have found that they can make chains of indium atoms linked by single bonds.



Bacterium's Sticky Solution
A harmless bacterium that lives in waterways could be using nature's strongest adhesive, according to findings by US researchers. Bacteriologist Yves Brun of Indiana University Bloomington and Brown University physicist Jay Tang and colleagues have identified a natural chemical produced by Caulobacter crescentus and found it to be one of the strongest glues known.

Oogling for ChemistsOogling for Chemists Chemists have often berated the online world for a lack of a straightforward search engine that allows them to search for chemical information quickly and easily.



Water wireWater, Water Understanding the often anomalous behavior of water could hang by a thread between a sharp silicon point and a mica surface, according to Korean scientists.


Red GlassDopey Red Glass People have been coloring glass for centuries. Even the ancient Romans knew that adding gold to glass would convert it into a ruby-red material when heated in a controlled fashion.



Peter Murray-RustPeter Murray-Rust, originally a crystallographer with a DPhil from Oxford, has worked at the University of Ghana, the University of Stirling, and at Glaxo where he developed new technologies including molecular graphics, protein structure determination, and intranets. He ran the first multimedia virtual course on the Web (Principles of Protein Structure) at Birkbeck College London and was a virtual chemist at Nottingham University.


Hydrophobic Water?Hydrophobic Water? That old truism about mixing oil and water can apply to water and water, according to researchers at Pacific Northwest National Laboratory in Washington State.


SpermFertility Threat Acquittal for PCBs Polychlorinated biphenyls (PCBs), may damage sperm. However, despite this PCBs do not have dramatic effects on human fertility.


Synthetic resilinSuper Rubber Made in Leaps and Bounds  Australian scientists have more than scratched the surface to synthesise a polymer based on an elastic protein called resilin that endows the flea with record-breaking leaping prowess.


Hurricane KatrinaKatrina and the Waves  The floodwaters that inundated New Orleans after Hurricane Katrina were not as toxic to humans as previously thought. The findings published by researchers at Louisiana State University are good news for those who were exposed directly to the floodwaters, although say nothing of the physical devastation caused by the flood.

Nickel gallium sulfideLiquid Magnets Nickel gallium sulfide (NiGa2S4) may behave as a highly unusual "liquid" magnetic material at near absolute zero, according to Japanese and US researchers.