Spectral Analysis

amplitude-spectroscopyThis week in my SpectroscopyNOW column, I have four new posts covering, as usual, a wide range of solutions to scientific and technical problems. First up, is the discovery that compounds found in cannabis could lead to novel antibiotics that are less susceptible to resistance than conventional drugs. Then, we have a new type of spectroscopy that allows scientists to carry out broadband analysis of artificial atoms held at temperatures close to absolute zero. Next, is word from chemists that they have developed a new type of reaction flask that can carry out reactions in the solid state. Finally, this week, we hear of testing times for biomass, where modern spectral analysis could help in the processing of old, treated wood as a renewable fuel resource.

Doping the superbugs – Substances found in cannabis could be used to fight potentially lethal superbugs, such as antibiotic-resistant bacteria, without the mood-altering effects, according to researchers in Italy and the UK. Cannabis sativa (L. Cannabinaceae) extracts may also provide an alternative to synthetic antibacterial substances used in personal hygiene products, including hand wash and cosmetics.

Diamond amp – A new spectroscopic approach to measuring the energy levels of an atomic system has been developed by US researchers. Amplitude spectroscopy can be used to measure the energies of certain natural and artificial atoms and molecules over extremely broad bandwidth by scanning the amplitude of the applied radiation rather than its frequency. The new technique allows the characterization of multiple energy levels in the system, and so overcomes a key challenge to realization of powerful quantum computers. It is applicable to systems with strong coupling to external fields, including artificial atoms, spin systems, cold atoms and molecules, and molecular magnets.

Littlest test-tube – Chemists in Japan have synthesized a new porous material that acts as a microscopic solid-state reaction vessel. Chemical changes taking place in each pore can be tracked using X-ray crystallography the team explains.

Testing times for biomass – Spectroscopy can be used to determine the amount of ash and char present in various types of biomass derived from wood, according to researchers in Japan and the US. Their analytical approach could help in the development of renewable resources for fuels to replace fossil fuels.

Melamine Scandal Widens

chinese-babyFour infants in China have died and at least 53,000 are reportedly ill, many seriously so, having been fed milk powder contaminated with the industrial chemical melamine. A three-year old girl in Hong Kong is also ill, but has now been released from hospital, she was the first reported case outside mainland China. Major formula milk producer Nestle says none of its products in China has been contaminated with melamine, although the Hong Kong government says it has found the contaminant in the company’s milk formula.

I guess it’s no surprise that this scandal has emerged after, rather than before or during, the Olympic Games, but that is not something that would be peculiar to China. Governments the world over try to manage bad news and China certainly does not have a monopoly on cover-ups. If melamine is the primary contaminant, then regardless of claims that other compounds may be present, long-term use (six months or so) would be enough for this toxic compound to accumulate in an infant and lead to toxic effects such as kidney stones. The LD50, or acute toxic dose is not entirely relevant if an infant is being fed contaminated milk day after day. Incidentally, LD50 is a measurement per kilogram of body mass, so it is not higher for people than it is for rats, although it may be different because of differences in our body’s biochemistry.

I used to use an analytical instrument when I worked part-time in quality control in a milk-processing plant during my early post-student days. The machine could give you an almost instantaneous printout of fat, protein and sugar levels in the milk passing through the dairy. Those in QC also had to look at the milk for colour and quality and smell and taste it to check for taints (from pipe disinfectants, bacterial action, or contaminants). Indeed, one of the qualifications for the job was to have a palate sensitive enough to detect phenolic (smoky) compounds down to a few parts. It would usually have been quickly apparent if there was a problem with any incoming milk supply and I cannot see how others in the supply chain in China were not duplicitous in this conspiracy.

There could, of course, be other contaminants, I alluded to that in the original melamine in milk post. If someone is unscrupulous enough to add melamine to baby milk to falsify protein levels, then there’s no reason to think that they would use expensive chemically pure material. This would go some way to answering one of the questions asked by a commenter on the original post. Apparently, the Chinese government reported findings 2565 ppm or 0.25% of melamine in Sanlu’s milk powder. The cost of melamine is relatively high, so what would be the economic justification for such an irresponsible act if it were only increasing the apparent protein level by 1.2%?

The melamine may have been obtained from low-quality sources that are themselves contaminated with other toxic compounds, or it may be high-quality melamine, but stolen to order at some point in the supply chain? It has been suggested that other contaminants may be urea and aminopterin, but I have not seen any official note on that anywhere.

Melamine decomposes on heating, so one commenter on the original post was curious as to how does melamine survive the pasteurization and evaporation processes without decomposition used to make milk powder from raw milk.

Apparently, melamine has been mentioned in dispatches across China for more than 15 years, why is it that a pet food scare in 2007, and now this infant formula milk scandal are the only times that the western media has covered the problem?

nissin-cha-cha-dessertIt is becoming apparent that contaminated baby formula is not the only problem. Milk, ice cream, yoghurt, confectionery such as chocolates, biscuits and sweets, as well as any foods containing milk from China have been banned from import into Singapore after the country’s agri-food and veterinary authority found melamine in imported samples. Similarly, Taiwanese authorities seized imported products after notification of contamination from Beijing earlier this month. Japan has recalled various products. Canada’s Food Inspection Agency has warned citizens not to eat a dessert – Nissin Cha Cha Dessert – imported from China that has been found to be contaminated with melamine. The authorities in the Philippines are currently testing.

It is curious, but perhaps not surprising, that the Chinese authorities say not a single hospitalisation case has any connection with contaminated milk. Fonterra, parent company of milk producer Sanlu which is at the centre of the scandal says the whole debacle is one of sabotage and that there is no point in the production process at which melamine could have been added. Fonterra chief executive Andrew Ferrier claims an unknown third party put the banned chemical melamine into raw milk supplied to Sanlu. However, the company new about the contamination on August 2, just ahead of the Olympic Games, and claims that Chinese regulations prevented it from going public at the time.

RELATED: Melamine in Milk, this was the original item I posted on the melamine in milk scandal. I’ve also added an UPDATE: Milky Melamine, dated 2008-09-29.

Autumn Leaves

autumn-lakeToday, is the first day of autumn, the fall, and Google is celebrating with a new leafy logo. But, why do leaves turn red in the fall? It’s all down to chemistry. Red pigments known as anthocyanins form in leaves from many plant and tree species at the same time as the green photosynthetic apparatus is dismantled by the plant. During this process nutrients containing nitrogen (N) and phosphorus (P) are re-absorbed by the plant from its leaves for winter storage and the plant’s waste products in the leaves are left behind. If these nutrients are not resorbed next year’s growth is inhibited. As the levels of green compounds in the leaf falls and anthocyanins rise so the leaves of many species change from verdant to rusty with a range of colours in between. In one sense (according to my high school biology teacher, Mrs Bradley [no relation], the trees are “urinating”, or more strictly, excreting waste in the annual fall.

red-leavesFor more information on why leaves turn red in autumn, check out this page from Wisconsin University. Science Made Simple has a nice explanation too as does Dr David Wilkinson from Liverpool John Moore’s University, and the USDA.

As an adjunct to this PNAS has just published a paper that reveals the enzymiccascade that controls abscission, the process that determines how and when plants actually shed their leaves:

S. K. Cho, C. T. Larue, D. Chevalier, H. Wang, T.-L. Jinn, S. Zhang, J. C. Walker (2008). Regulation of floral organ abscission in Arabidopsis thaliana Proceedings of the National Academy of Sciences DOI: 10.1073/pnas.0805539105

Autumn Leaves is a jazz classic about the bittersweet symphony that’s life. My singing group Big Mouth cover it in a medley of standards. I’ve created a playlist of the other songs we cover, on Youtube, these are either original versions or, as Jon points out, oddities.

This is an updated post Sciencebase from November 2006. Hope you enjoy my new photos too, top one is a snap I took in the English Lake District one autumn, the second leafy view is of a tree at Anglesey Abbey in Cambridgeshire.

Revisiting Chernobyl

chernobyl-nuclear-power-plantChernobyl. The very name strikes fear into the hearts of those who hate everything about the nuclear industry. It conjures up images of an archaic, burning industrial site spewing out lethal fumes, of farm animals dying of radiation poisoning in their thousands and contaminated meat, of ecosystems devastated, and of people with radiation sickness and for those spared the acutely fatal toxicity, the prospect of cancers to come and perhaps generations of mutations. But…

Korean researchers argue that while the 1986 accident at the Chernobyl nuclear power plant, Ukraine, was the worst catastrophe involving radiation to humans, but has led to an unfortunate and unwarranted degree of radio-anxiety. It is not radiation that is the health issue, but this anxiety.

Chong-Soon Kim of the Korea Institute of Radiological and Medical Sciences and colleagues say that despite warnings of pent up health problems from Greenpeace and the World Health Organisation (WHO), “there is no convincing evidence that the incidence of leukaemia or solid cancers have increased in the exposed populations.” They add that the apparent evidence of decreased fertility and increased hereditary effects has not been observed in the general population despite claims to the contrary.

According to the WHO, some 4000 people – emergency workers and residents – died or could die in the future because of Chernobyl. Greenpeace insists that this figure is almost 100,000 across the globe. Kim and colleagues point out first that although the incidence of thyroid cancer has increased in the Chernobyl area, it is actually regions less contaminated by radiation where the greatest incidence has been reported.

“In this case we have to be cautious on the point that the results came from extrapolation using insufficient individual doses, and so far deaths from cancer have not been reported as predicted,” say Kim and colleagues.

The radiation exposure level is the most important factor to estimate the cancer risk due to the Chernobyl accident. There are three types of exposed people. First, the exposure of recovery operation workers ranged up to about 500 millisieverts for a short period after the accident, with an average of about 100 mSv. In the case of evacuees, the average dose estimate of Ukrainian evacuees is 17 mSv (range 0.1-380 mSv), and the estimate for the Belarusian evacuees is 31 mSv, with a maximum of about 300 mSv. The average effective dose estimate of the general population in contaminated areas from 1986 to 2005 (some 5 million people) is 10-20 mSv.

The impact of Chernobyl on mental health and the future of nuclear as a viable renewable energy industry with public support, is perhaps the most serious problem. Among residents of the region and the emergency workers major psychological problems, such as depression, anxiety, and post-traumatic stress disorder are common. Anxiety levels are reported to be twice as high as in controls, the researchers say.

“Health effects, including cancer deaths, due to the Chernobyl accident have not reached the serious situation that was predicted,” the researchers say. There is, of course, some uncertainty in these figures although solid cancers usually form over a fifteen year period, rather than twenty years.

Young Woo Jin, Meeseon Jeong, Kieun Moon, Kwang Hee Yang, Byung Il Lee, Hun Baek, Sang Gu Lee, Chong Soon Kim (2008). Health effects 20 years after the Chernobyl accident International Journal of Low Radiation, 5 (3) DOI: 10.1504/IJLR.2008.020255

Melamine in Milk

melamine-structure-3DUPDATE: Melamine Milk Update, January 22, 2009

Sciencebase will be keeping you updated on the melamine scandal with opinion from the experts and the latest news on the story as it unfolds.

Several thousand babies in China became ill, having apparently suffered acute kidney failure, with several fatalities, having been fed formula milk allegedly contaminated with the industrial chemical melamine. The toll is far higher than was previously admitted by the Chinese authorities, according to the BBC. Click here for a list of melamine contaminated products.

One manufacturer recalled all of its powdered milk products in China’s north-west province of Gansu. However, twenty-two brands of milk powder were quickly identified as containing melamine. “The majority of afflicted infants ingested [the] milk powder over a long period of time, their clinical symptoms showed up three to six months after ingesting the problematic products,” Health Minister Chen Zhu told Bloomberg Asia.

Allegedly, someone in the supply change, milk supplier or manufacturer, was adding melamine to the milk formula to artificially inflate the reading for protein levels. Formula milk was not until now tested for melamine, because regulators did not suspect this ingredient might be added. But, it turns out that melamine in the food supply is China’s big open secret.

So, what is melamine and how does it spoof the protein levels in baby formula milk?

melamine-structureMelamine is an organic compound, a base with the formula C3H6N6. Officially it is 1,3,5-triazine-2,4,6-triamine in the IUPAC nomenclature system (CAS #108-78-1). It is has a molecular mass of just over 126, forms a white, crystalline powder, and is only slightly soluble in water. It is used in fire retardants in polymer resins because its high nitrogen content is released as flame-stifling nitrogen gas when the compound is burned or charred.

Indeed, it is this high nitrogen level – 66% nitrogen by mass – in melamine that gives it the analytical characteristics of protein molecules. Melamine can also be described as a trimer of cyanamide, three cyanamide units joined in a ring. It is described as being harmful according to its MSDS sheet: “Harmful if swallowed, inhaled or absorbed through the skin. Chronic exposure may cause cancer or reproductive damage. Eye, skin and respiratory irritant.” Not something you would want in your infant’s milk. However, that said, the toxic dose is rather high, on a par with common table salt with an LD50 of more than 3 grams per kilogram of bodyweight.

Previously, melamine was found in exported pet food last year and blamed for killing thousands of cats and dogs in the US. Bloomberg also reports that analysis of samples of ice cream produced by one company have also revealed the presence of melamine. Regardless of crushing inflation and legislative pressure, there is no excuse for the adulteration of food in this way. Diluting a product, the previous approach, is highly unethical and can lead to malnutrition, but straight poisoning is tantamount infanticide. This is also not the first time that Chinese consumers have faced problems with milk powder. In 2004, more than a dozen children died having been fed formula with minimal nutritional content.

But, if melamine has low toxicity (hat tip to commenter Barney) then what is it that has poisoned thousands of babies in China and why has this scandal occurred? Well, LD50, the toxic dose issue, tells us something about acute exposure not the apparent six-months’ worth of accumulated exposure these babies have suffered. Chronic exposure to melamine can lead to bladder or kidney stones and even bladder cancer and as we have learned, acute kidney failure. Health problems such as these can land you in the hospital. Most treatments cannot be given at home, therefore you will not have the comfort of your couch or bed. Many hospitals do not have the luxury of offering ergo mattresses to their patients.

The melamine in milk headlines also ignore the fact that the compound added to the milk may not be pure. There is no reason to imagine that those unscrupulous enough to add a toxic compound to baby formula milk would worry about contaminants, such as cyanuric acid, that might be found in the raw material. Indeed, even if melamine toxicity were not an issue and truly was an inert substance added to spike the protein readings in quality control tests, then any one of the impurities associated with rough melamine manufacture may be a major cause for concern.

UPDATES: A melamine apology from the Chinese premier, Melamine Scandal Widens and Milky Melamine, melamine and kidney failure.

Spray-on Condoms

condom-sprayAs a kind of follow-up to my Sex and Social Networking post last week, I thought I’d give a mention to the ludicrous idea of spray-on condoms highlighted, in lurid yellow on Geeks are Sexy this week.

This supposedly original idea of applying Latex in spray-on form looks like an April Fool’s joke. First off, it’s not a new idea, especially given the range of colours the inventor is working with. I have heard of several patent applications for similar approaches to contraception and safer sex over the years, they even get a mention in Ben Elton’s book This Other Eden. The idea is fatally flawed on several fronts.

In the heat of passion, I suspect that producing a laboratory-standard uniform layer with no weak points will be impossible and therefore make the device ineffective. However, entanglement of the material with pubic hair would also be a serious issue at the time of desheathing. It’s bad enough removing a band-aid from a grazed knee, but this has the potential to cause much worse pain.

I assume that the process will be safety tested before it is made commercially available, but there are certain characteristics of an aerosol spray that could not be avoided. Primarily, the sprayer and teh sprayee are liable to be breathing more heavily than usual, to have slightly raised blood pressure, and perhaps be open mouthed. The last thing you would want to be near in such circumstances is close to airborne Latex – think potential inhalation, anaphylactic shock and risk of death.

Such a spray would almost certainly be designed for external use only, and yet the organ destined to be coated not only has delicate surface tissues, but an aperture through which particles and carrier solvent might enter. Penile contact dermatitis anyone? Didn’t think so!

And, speaking of solvents, presumably there will be a carrier solvent in which the Latex will be suspended and transported from spraycan to the surface to be coated. The phrase latent heat of evaporation comes to mind and its attendant rapid chilling effect, so there is also potential for frost-bite or at best stinging pain.

There is perhaps one advantage not noted for this approach to condom application, which may benefit some and that is to do with the issue of size becoming irrelevant…no need to distinguish big, large, or extra large, unless, of course, you run out of spray attempting to get 100% coverage.

One more issue. As you can see from the photo of the inventor creating a condom-shaped mess, the process of applying a spray-on condom does not look like a particularly neat and tidy one. If you have ever had difficulty explaining lipstick on your collar, then you will definitely struggle to explain a lurid yellow smear of rubber on your underwear. It almost makes abstinence seem like a viable option.

Top Trumps for Science Competition

top-trumps-scienceSomething a little different today. A tale of family playtime, a poll, and a competition to win prizes from the RSC and the CentreoftheCell.org.

Card Competition

Okay, here’s the competition bit. What you have to do to be in with a chance of winning is to drop me a line, giving me a good reason (in not more than 15 words) for your choice of chemical trumps or cell trumps and you win the pack of your choice – trumpcomp-AT-sciencebase.com is the address to use.

I’ll pick the best ideas from the comments and emails and announce the winner in the next few weeks. Judge’s decision will be final and if no entries come up to scratch then I reserve the right to throw my rattle out of the pram.

And, now on with the story…

This term, both my kids are learning about the elements at school. My daughter, who is still in primary school is learning about the ancient elements – earth, air, fire, water. While my son, who is half way through high school returned home with tales of electron shells and the elements of the periodic table.

It was, therefore quite timely that Royal Society of Chemistry press officer and Satrianialike, Jon Edwards, should send me a pack of Visual Elements Trumps. The cards follow in the classic tradition of the Top Trumps game, my friends and I collected and played when we were at school – trains, planes, automobiles and a few more sciencey ones, including dinosaurs were around at that time. There have been others since, including a spinoff from the defunct BBC TV show and magazine Tomorrow’s World, Star Wars, and Harry Potter have also fallen under the trumping spell. And, of course, Pokemon and Digimon cards, which swept through playground a few years ago, are also based on the trump theme, albeit with a few more bizarre properties than top speed and height.

Anyway, the kids and I had a quick round of Elemental trumps. My daughter won, having quickly latched on to the notions of automatic atomic radius and ionistation ionisation energy. She was also rather intrigued by the idea of hydrogen gas having a boiling point. We all enjoyed the game, but obviously it’s the educational and promotional value it may have for kids studying science and chemistry that underpin its production by the RSC. I have to admit the writing in the element description bubble is too small for me to see in dim light. With a magnifying glass, however, I can see that they have packed the main elemental essentials on to each card together with the RSC’s well-known artistic images associated with each.

A related product on the science educational stuff market is Elementeo, which is a hybrid of sword & sorcery game and science, with a Sodium Dragon and Oxygen the Lifegiver. They’re very tongue in cheek but there’s not as much chemical information. So unless you’re a science fantasy addict, I’d opt for the RSC game. Another variation on the theme is available from the WebElements shop and was developed by the University of Brighton. This version has more facts and also comes with approval (for what that’s worth) from the Top Trumps people .

We then moved on to a game of Cell Trumps, produced by the Centre of the Cell at Queen Mary University of London, which arrived at roughly the same time as the RSC cards. However, a quick fan of the deck reveals them to be slightly simpler, swapping number in body for 1st ionisation energy, and number of their scientists working on the particular type of cell for atomic radius. But the kids coped, although my daughter favoured the slightly more esoteric Element Trumps over the cell. She was quite taken by the adipocytes having spotted the connection with the name of the fatty, alien Adipose characters from a recent Doctor Who episode.

Scientific Trumps seemed just right for introducing some scientific concepts in a fun way to kids at the higher end of primary school or even heading towards high school exams. They might even be inspirational to money-free undergraduates lacking beer towards the end of term, who knows? And, if you arrived here looking for science education materials check out the learn with Sciencebase page, which has links to various science project resources.

Sex and Social Networking

social-sexUltimately, the only truly safe sex is that practised alone or not practiced at all, oh, and perhaps cybersex. However, that said, even these have issues associated with eyesight compromise (allegedly), repetitive strain injury (RSI) and even electrocution in extreme cases of online interactions (you could spill your Mountain Dew on your laptop, after all). And, of course, there are popups, Trojans, packet sniffers and viruses and worms to consider…

No matter how realistic the graphics become in Second Life or how good the 3rd party applications in Facebook, however, unless you indulge in direct human to human contact in the offline world, you are not going to catch a sexually transmitted disease, STD. Real-world social networking is, of course, a very real risk factor for STD transmission, according to a new research report in the International Journal of Functional Informatics and Personalised Medicine. This could be especially so given the concept of six five-degrees of separation through which links between individuals are networked by ever short person-to-person-to-person bonds.

According to Courtney Corley and Armin Mikler of the Computational Epidemiology Research Laboratory, at the University of North Texas, computer scientist Diane Cook of Washington State University, in Pullman, and biostatistician Karan Singh of the University of North Texas Health Science Center, in Fort Worth, sexually transmitted diseases and infections are, by definition, transferred among intimate social networks.

They point out that although the way in which various social settings are formed varies considerably between different groups in different places, crucial to the emergence of sexual relationships is obviously a high level of intimacy. They explain that for this reason, modelling the spread of STDs so that medical workers and researchers can better understand, treat and prevent them must be underpinned by social network simulation.

Sexually transmitted diseases and infections are a significant and increasing threat among both developed and developing countries around the world, causing varying degrees of mortality and morbidity in all populations.

Other research has revealed that approximately one in four teens in the United States will contract a sexually transmitted disease (STD) because they fail to use condoms consistently and routinely. The reasons why are well known it seems – partner disapproval and concerns of reduced sexual pleasure.

As such, professionals within the public health industry must be responsible for properly and effectively funding resources, based on predictive models so that STDs can be tamed. If they are not, Corley and colleagues suggest, preventable and curable STDs will ultimately become endemic within the general population.

The team has now developed the Dynamic Social Network of Intimate Contacts (DynSNIC). This program is a simulator that embodies the intimate dynamic and evolving social networks related to the transmission of STDs. They suggest that health professionals will be able to use DynSNIC to develop public health policies and strategies for limiting the spread of STDs, through educational and awareness campaigns.

As a footnote to this research, it occurred to me that researchers must spend an awful lot of time contriving acronyms and abbreviations for their research projects. Take Atlas, one of the experimental setups at the Large Hadron Collider at CERN in Geneva Switzerland. Atlas stands for – “A Toroidal LHC ApparatuS”. So they used an abbreviation within their acronym as well as a noise word – “A” and the last letter of one of the terms. Ludicrous.

But, Atlas is not nearly as silly as the DynSNIC acronym used in Corley’s paper, I’m afraid. Dynamic Social Network of Intimate Contacts, indeed! I thought the whole idea of abbreviating a long research project title was to make it easier to remember and say out lead. DynSNIC, hardly memorable (I is it a y or an I, snic or snick or sink or what. Students will forever struggle with such contrivances. They could’ve just as easily used something like Sexually Transmitted Infections Contact Social Intimate Networks – STICSIN. This would be a double-edged sword that would appeal to both to the religious right and to the scabrous-minded, depending where you put the break (after the Contact or after Social.

Courtney D. Corley, Armin R. Mikler, Diane J. Cook, Karan P. Singh (2008). Dynamic intimate contact social networks and epidemic interventions International Journal of Functional Informatics and Personalised Medicine, 1 (2), 171-188

What on earth and off earth is dark energy?

TL:DR – A reprint of a feature article of mine on Dark Energy that was published in StarDate magazin in July 2007.


Type 1a Supernova Credit: NASA/Swift/S. Immler)Forget the Large Hadron Collider (LHC), with its alleged ability to create earth-sucking microscopic black holes, its forthcoming efforts to simulate conditions a trillionth of a second after the Big Bang 100 metres beneath the Swiss countryside. There is a far bigger puzzle facing science that the LHC cannot answer: What is the mysterious energy that seems to be accelerating ancient supernovae at the farthest reaches of the universe?

In the late 1990s, the universe changed. The sums suddenly did not add up. Observations of the remnants of stars that exploded billions of years ago, Type Ia supernovae, showed that not only are they getting further away as the universe expands but they are moving faster and faster. It is as if a mysterious invisible force works against gravity and pervades the cosmos accelerating the expansion of the universe. This force has become known as dark energy and although it apparently fills the universe, scientists have absolutely no idea what it is or where it comes from, several big research teams around the globe are working with astronomical technology that could help them find an answer.

Until type Ia supernovae appeared on the cosmological scene, scientists thought that the expansion of the universe following the Big Bang was slowing down. Type Ia supernovae are very distant objects, which means their light has taken billions of years to reach us. But, their brightness could be measured to a high degree of accuracy that they provide astronomers with a standard beacon with which the vast emptiness of space could be illuminated, figuratively speaking.

The supernovae data, obtained by the High-Z SN Search team and the Supernova Cosmology Project, rooted in Lawrence Berkeley National Laboratory, suggested that not only is the universe expanding, but that this expansion is accelerating. to make On the basis of the Type Ia supernovae, the rate of acceleration of expansion suggests that dark energy comprises around 73% the total energy of the universe, with dark matter representing 24% of the energy and all the planets, stars, galaxies, black holes, etc containing a mere 4%.

HETDEX, TEX STYLE

Professor Karl Gebhardt and Senior Research Scientists Dr Gary Hill and Dr Phillip McQueen and their colleagues running the Hobby Eberly Telescope Dark Energy Experiment (HETDEX) based at the McDonald Observatory in Texas are among the pioneers hoping to reveal the source and nature of dark energy. Those ancient supernovae are at a “look-back time” of 9 billion years, just two-thirds the universe’s age. HETDEX will look back much further to 10 -12 billion years.

HETDEX DomeHETDEX will not be looking for dark energy itself but its effects on how matter is distributed. “In the very early Universe, matter was spread out in peaks and troughs, like ripples on a pond, galaxies that later formed inherited that pattern,” Gebhardt explains. A detailed 3D map of the galaxies should reveal the pattern. “HETDEX uses the characteristic pattern of ripples as a fixed ruler that expands with the universe,” explains Senior Research Scientist Gary Hill. Measuring the distribution of galaxies uses this ruler to map out the positions of the galaxies, but this needs a lot of telescope time and a powerful new instrument. “Essentially we are just making a very big map [across some 15 billion cubic light years] of where the galaxies are and then analyzing that map to reveal the characteristic patterns,” Hill adds.

“We’ve designed an upgrade that allows the HET to observe 30 times more sky at a time than it is currently able to do,” he says. HETDEX will produce much clearer images and work much better than previous instruments, says McQueen. Such a large field of view needs technology that can analyze the light from those distant galaxies very precisely. There will be 145 such detectors, known as spectrographs, which will simultaneously gather the light from tens of thousands of fibers. “When light from a galaxy falls on one of the fibers its position and distance are measured very accurately,” adds Hill.

The team has dubbed the suite of spectrographs VIRUS. “It is a very powerful and efficient instrument for this work,” adds Hill, “but is simplified by making many copies of the simple spectrograph. This replication greatly reduces costs and risk as well.”

McQueen adds that after designing VIRUS, the team has built a prototype of one of the 145 unit spectrographs. VIRUS-P is now operational on the Observatory’s Harlan J. Smith 2.7 m telescope, he told us, “We’re delighted with its performance, and it’s given us real confidence in this part of our experiment.”

VIRUS will make observations of 10,000 galaxies every night. So, after just 100 nights VIRUS will have mapped a million galaxies. “We need a powerful telescope to undertake the DEX survey as quickly as possible,” adds McQueen. Such a map will constrain the expansion of the universe very precisely. “Since dark energy only manifests itself in the expansion of the universe, HETDEX will measure the effect of dark energy to within one percent,” Gebhardt says. The map will allow the team to determine whether the presence of dark energy across the universe has had a constant effect or whether dark energy itself evolves over time.

“If dark energy’s contribution to the expansion of the universe has changed over time, we expect HETDEX to see the change [in its observations],” adds Gebhardt, “Such a result will have profound implications for the nature of dark energy, since it will be something significantly different than what Einstein proposed.”

SLOAN RANGER

Scientific scrutiny of the original results has been so intense that most cosmologists are convinced dark energy exists. “There was a big change in our understanding around 2003-2004 as a triangle of evidence emerged,” says Bob Nichol of the University of Portsmouth, England, who is working on several projects investigating dark energy.

SDSS M51

First, the microwave background, the so-called afterglow of creation, showed that the geometry of the universe has a mathematically “flat” structure. Secondly, the data from the Type Ia supernovae measurements show that the expansion is accelerating. Thirdly, results from the Anglo-Australian 2dF redshift survey and then the Sloan Digital Sky Survey (SDSS) showed that on the large scale, the universe is lumpy with huge clusters of galaxies spread across the universe.

The SDSS carried out the biggest galaxy survey to date and confirmed gravity’s role in the expansion structures in the universe by looking at the ripples of the Big Bang across the cosmic ocean. “We are now seeing the corresponding cosmic ripples in the SDSS galaxy maps,” Daniel Eisenstein of the University of Arizona has said, “Seeing the same ripples in the early universe and the relatively nearby galaxies is smoking-gun evidence that the distribution of galaxies today grew via gravity.”

But why did an initially smooth universe become our lumpy cosmos of galaxies and galaxy clusters? An explanation of how this lumpiness arose might not only help explain the evolution of the early universe, but could shed new light on its continued evolution and its ultimate fate. SDSS project will provide new insights into the nature of dark energy’s materialistic counterpart, dark matter.

As with dark energy, dark matter is a mystery. Scientists believe it exists because without it the theories that explain our observations of how galaxies behave would not stack up. Dark matter is so important to these calculations, that a value for all the mass of the universe five times bigger than the sum of all the ordinary matter has to be added to the equations to make them work. While dark energy could explain the accelerating acceleration our expanding universe, the existence of dark matter could provide an explanation for how the lumpiness arose.

“In the early universe, the interaction between gravity and pressure caused a region of space with more ordinary matter than average to oscillate, sending out waves very much like the ripples in a pond when you throw in a pebble,” Nichol, who is part of the SDSS team, explains. “These ripples in matter grew for a million years until the universe cooled enough to freeze them in place. What we now see in the SDSS galaxy data is the imprint of these ripples billions of years later.”

Colleague Idit Zehavi now at Case Western University adds a different tone. Gravity’s signature could be likened to the resonance of a bell she suggests, “The last ring gets forever quieter and deeper in tone as the universe expands.” It is now so faint as to be detectable only by the most sensitive surveys. The SDSS has measured the tone of this last ring very accurately.”

“Comparing the measured value with that predicted by theory allows us to determine how fast the Universe is expanding,” explains Zehavi. This, as we have seen, depends on the amount of both dark matter and dark energy.

The triangle of evidence – microwave background, type Ia supernovae, and galactic large-scale structure – leads to only one possible conclusion: that there is not enough ordinary matter in the universe to make it behave in the way we observe and there is not enough normal energy to make it accelerate as it does. “The observations have forced us, unwillingly, into a corner,” says Nichol, “dark energy has to exist, but we do not yet know what it is.”

The next phase of SDSS research will be carried out by an international collaboration and sharpen the triangle still further along with the HETDEX results. “HETDEX adds greatly to the triangle of evidence for dark energy,” adds Hill, “because it measures large-scale structure at much greater look-back times between local measurements and the much older cosmic microwave background,” says Hill. As the results emerge, scientists might face the possibility that dark energy has changed over time or it may present evidence that requires modifications to the theory of gravity instead.

Wiggle-Z

The Anglo-Australian team is also undertaking its own cosmic ripple experiment, Wiggle-Z. “This program is measuring the size of ripples in the Universe when the Universe was about 7 billion years old,” Brian Schmidt at Australian National University says. Schmidt was leader of the High-Z supernovae team that found the first accelerating evidence. SDSS and 2dF covered 1-2 billion years ago and HETDEX will measure ripples at 10 billion years. “Together they provide the best possible measure of what the Universe has been doing over the past several years,” Schmidt muses.

INTERNATIONAL SURVEY

The Dark Energy Survey, another international collaboration, will make any photographer green with envy, but thankful they don’t have to carry it with them. The Fermilab team plans to build an extremely sensitive 500 Megapixel camera, with a 1 meter diameter and a 2.2 degree field of view that can grab those millions of pixels within seconds.

The camera itself will be mounted in a cage at the prime focus of the Blanco 4-meter telescope at Cerro Tololo Inter-American Observatory, a southern hemisphere telescope owned and operated by the National Optical Astronomy Observatory (NOAO). This instrument, while being available to the wider astronomical community, will provide the team with the necessary power to conduct a large scale sky survey.

Over five years, DES will use almost a third of the available telescope time to carry out its wide survey. The team hopes to achieve exceptional precision in measuring the properties of dark energy using counts of galaxy clusters, supernovae, large-scale galaxy clustering, and measurements of how light from distant objects is bent by the gravity of closer objects between it and the earth. By probing dark energy using four different methods, the Dark Energy Survey will also double check for errors, according to team member Joshua Frieman.

WFMOS

Subaru 51

According to Nichol, “The discovery of dark energy is very exciting because it has rocked the whole of science to its foundations.” Nichol is part of the WFMOS (wide field multi-object spectrograph) team hoping to build an array of spectrographs for the Subaru telescopes. These spectrographs will make observations of millions of galaxies across an enormous volume of space at a distances equivalent to almost two thirds the age of the universe. “Our results will sit between the very accurate HETDEX measurements and the next generation SDSS results coming in the next five years,” he explains, “All the techniques are complimentary to one another, and will ultimately help us understand dark energy.”

DESTINY’S CHILD

If earth-based studies have begun to reveal the secrets of dark energy, then three projects vying for attention could take the experiments off-planet to get a slightly closer look. The projects all hope to look at supernovae and the large-scale spread of matter. They will be less error prone than any single technique and so provide definitive results.

SNAP, SuperNova/Acceleration Probe, is led by Saul Perlmutter of Lawrence Berkeley National Laboratory in Berkeley, California, one of the original supernova explorers. SNAP will observe light from thousands of Type Ia supernovae in the visible and infra-red regions of the spectrum as well as look at how that light is distorted by massive objects in between the supernovae and the earth.

Adept, Advanced Dark Energy Physics Telescope, is led by Charles Bennett of Johns Hopkins University in Baltimore, Maryland. This mission will also look at near-infrared light from 100 million galaxies and a thousand Type Ia supernovae. It will look for those cosmic ripples and so map out the positions of millions of galaxies. This information will allow scientists to track how the universe has changed over billions of years and the role played by dark energy.

Destiny, Dark Energy Space Telescope, led by Tod Lauer of the National Optical Astronomy Observatory, based in Tucson, Arizona, will detect and observe more than 3000 supernovae over a two-year mission and then survey a vast region of space looking at the lumpiness of the universe.

LIGHTS OUT ON DARK ENERGY

So, what is dark energy? “At this point it is pure speculation,” answers Hill, “The observations are currently too poor, so we are focusing on making the most accurate measurements possible.” Many scientists are rather embarrassed but equally excited by the thought that we understand only a tiny fraction of the universe. Understanding dark matter and dark energy is one of the most exciting quests in science. “Right now, we have no idea where it will lead, adds Hill.

Supernovae (NASA collage)

“Despite some lingering doubts, it looks like we are stuck with the accelerating universe,” says Schmidt. “The observations from supernovae, large-scale structure, and the cosmic microwave background look watertight,” he says. He too concedes that science is left guessing. The simplest solution is that dark energy was formed along with the universe. The heretical solution would mean modifying Einstein’s theory of General Relativity, which has so far been a perfect predictor of nature. “Theories abound,” Schmidt adds, “whatever the solution, it is exciting, but a very, very hard problem to solve.”

This David Bradley special feature article originally appeared on Sciencebase last summer, having been published in print in StarDate magazine – 2007-07-01-21:12:X1

Night at the Web Museum

night-at-the-museumYears ago when BioMedNet’s HMSBeagle was still sailing the high seas, I wrote a feature for the Adapt or Die careers column on scientific jobs in museums, the feature, which is available on Sciencebase is still relatively valid, but one big aspect of museums that has changed significantly since the Beagle was abandoned in dry dock is that museums the world over have virtualised themselves.

It has reached the point now, that a museum without a web presence and moreover without a beautifully designed, powerful, comprehensive, informative and interactive web presence is no museum at all. I’m sure that curators the world over reading this will by now be gnashing their teeth, and if any of them have no teeth to grit, teeth will be provided.

Anyway, it’s not to say that a purely offline museum would not be attractive to passing trade. However, Thomas Fotakis and Anastasios Economides of the University of Macedonia, in Thessaloniki, Greece, a country of multiple museums to say the least, suggest that museums cannot afford to remain offline. In a rapidly evolving and changing society where the internet has become an almost ubiquitous tool and entertainment device museums – whether art, history, or science and technology – have to get online if they are to stay current. Moreover, they suggest that the creation of a virtual meta museum is the next logical step.

Museums should collaborate in order to develop a unified huge multimedia database that will contain all of their artefacts (either exhibited or in repository), information about art, culture, science, history, artists, exhibits, related events,” the researchers say.

Virtual and offline visitors would be able to search such a meta museum to find things of interest, participate in discussions with other visitors, and from the research point of view, unearth relationships between disparate artefacts in different parts of the world that may not be apparent to those merely browsing dusty shelves and cabinets in the offline world.

Through their websites, museums would create an environment in which visitors are not only able to explore the exhibited objects and art works, but also deal with new original experiences and ideas. Therefore, visitors can have a more essential and important experience.

But before that happens there are various concerns that have been raised about the web presence of almost all museums. For instance, many museum sites have been built without firm foundations and with no particular aims other than to create a web site. Further, many have never been assessed as to how well they actual meet their visitors’ needs and with no clear aim for the site, this is perhaps not surprising. Most worryingly though, is that much of the material on museum web sites simply duplicates in digital form the materials found in the bricks and mortar museums rather than rethink and developing the possibilities offered by the web. There are exceptions, of course.

Now, Fotakis and Economides have reviewed more than 200 museums having an online presence setting a range of criteria to reveal successes and to uncover problems. Their system, MuseumQual, provides a way to evaluate museum websites based on quality, quantity and most of all, user experience. “It is not enough to present a lot of information on the website,” they affirm, “It is also important that a visitor easily explores and utilises it.”

They tested 70 art, 70 science/technology, and 70 history museums using their program, looking at layout, multimedia, interactivity, feedback, and technical aspects such as whether or not a site force-fed the user browser cookies, had any “under construction” pages, privacy or security issues, and good navigation.

“Our evaluation showed that museums present websites that stay at a satisfying, yet not exceptional, level,” the researchers say, “Science museums’ sites lead the list, with art museums’ sites following closely and history museums’ sites coming in next. Almost all sites outperformed with respect to technical characteristics. However, many sites present inefficiencies regarding Interactivity and Feedback.”

They also emphasise that virtual museums have a role to play in providing access to people with special needs and unfortunately only few of the 210 sites tested provided access to culture, art and knowledge equally, having failed to account for people with alternative accessibility requirements. One aspect of accessibility could benefit anyone and that is the creation of virtual tours in the form of audio podcasts or video files or newsfeeds.

Nevertheless, having tested sites around the world, they specifically highlight the Miami Science Museum (www.miamisci.org), Fort Lauderdale Museum of Discovery and Science (www.mods.org), and Science Museum of Minnesota (www.smm.org) as offering a huge amount of practical and valuable information. Most scitech sites were easy to navigate and aesthetically pleasing, with Scitech Science Museum (www.scitech.org.au), Pusat Sains Negara Science Museum (www.psn.gov.my/en/) and Science Museum in London (www.sciencemuseum.org.uk) being particularly strong on multimedia. The best sites for interactivity and e-services were the Science Museum of Minnesota (www.smm.org) and Infoage Science Center (www.infoage.org).

The overall winners on all aspects of the MuseumQual analysis were:

  1. Museum of Fine Arts of Boston (www.mfa.org) (4.55/5.00)
  2. Centre Pompidou (www.centrepompidou.fr) (4.53/5.00)
  3. The Science Museum in London (www.sciencemuseum.org.uk) (4.48/5.00)

Some museums have been on the web for a decade or more but most, even the old hands, are failing to exploit the full potential of the modern multimedia internet. No one wants a museum that exists only in the past, it’s time to bring them together into the twenty-first century to enrich our lives whether in science, art or history. By doing so the virtual meta museum suggested by the University of Macedonia team will bring the past to life, in the most un-cliched sense.

I asked Economides about the possibility of using the test system for other types of website, science blogs for instance as it is open for anyone to use. “With some modifications (e.g. regarding e-services) MuseumQual could be used to also test other types of site,” he says, “However, other dimensions (e.g. usability, technical) are almost common for any type of site.” He points out that the tool is not automatic. “It is a quality framework that includes many criteria,” he explains,
“A user would use it to evaluate a website and consider the proposed criteria.”

Thomas Fotakis, Anastasios A. Economides (2008). Art, science/technology and history museums on the web International Journal of Digital Culture and Electronic Tourism, 1 (1) DOI: 10.1504/IJDCET.2008.020134