Hemp Help for Everglades

Atrazine structure

Atrazine, a herbicide, and some of its degradation products could seep into groundwater and impair water quality across the Florida Everglades, according to Scientists from the USDA-Agricultural Research Service (ARS) and University of Florida. The team reports details of its studies into specific groundwater risk from atrazine in the September issue of the Journal of Environmental Quality.

In the same report, Thomas Potter and colleagues also report how they may have discovered a solution to the potential problem – a herbaceous annual that grows to two meters: sunn hemp.

The studies focused on sweet corn production and investigated whether fields with a highly vigorous cover crop would reduce the impact of herbicide use on the environment. Sunn hemp planted during uncultivated summer periods was found to be effective in reducing weeds and leaching while at the same time enriching the soil. Sunn hemp, not to be confused with cannabis hemp, can be grown to prevent soil erosion, as high-protein forage. The older plants can be used to make cloth, twine, and rope.

InChI=1/C8H14ClN5/c1-4-10-7-12-6(9)13-8(14-7)11-5(2)3/h5H,4H2,1-3H3,(H2,10,11,12,13,14)/f/h10-11H

Chemical Summer

It’s a bumper summer special issue over on Reactive Reports, with an interview with Chemistry Central OA advocate Bryan Vickery and a stash of breaking chemistry stories

Bryan Vickery
Reactive Profile–Bryan Vickery, Chemistry Central
Bryan Vickery did his BSc and PhD in electrochemistry at Liverpool University, England, but eschewed damaged jeans and fume cupboards for the world of electronic publishing.

 

 

Attractive Changing Colors  Yadong Yin and colleagues at the University of California, Riverside, have discovered that a simple magnet can be used to change the color of nanoparticles of iron oxide in aqueous suspension.

 

 

 

Fairytale Insulin Substitute  People with type I diabetes could one day be prescribed an extract from pumpkins that will drastically cut their reliance on daily insulin injections.

 

 

Multichannel Microchemical Factory 
In the mid-nineties, microchemistry was set to revolutionize the chemical industry.

 

smoker 

No Munchies with Cannabinoid Antagonist  The pharmaceutical rimonabant latches on to the cannabinoid 1 (CB1) receptors in the brain and blocks their activity.

 

seagull 

Contaminated Seabirds  A new approach to monitoring seabirds for contamination with polychlorinated biphenyls (PCBs) and other persistent organic pollutants (POPs) has been developed by scientists in Japan.

Camera Courses

photo coupons lilyFor those of you who are interested in knowing a bit about my personal life, I’ve spent daytimes this week on a digital photography course (evenings and early mornings have been blogging and work as usual, which makes for a rather tiring week).

I’ve been taking photos for almost two decades and have acted as picture editor and image source for dozens of articles over the years, but I hoped to gain a few new insights into the process of photo composition from international press photographer Malcolm Clarke, who was running the course at my local community education centre.

It was the first time the centre had run the week long course as part of its internationally famous summer school. We had a great group of enthusiastic photographers and rattled through several hundred snaps each over the course of the week. The range of skills among the students was initially very diverse and the biggest improvements were seen among those fresher to photography than any of those who might have already had some claim to being old hands. Even those students with the simplest of compact digital cameras were producing quite excellent shots and certainly demonstrated that having an eye for a shot is far more important than having the right kit.

That said, some of the most detailed macro close-ups of insects and flowers on the final day, taken at Cambridge’s stunning Botanical Gardens, were mindblowing, especially one students shot of a common darter (a type of dragonfly, that is not a ruddy darter) and another’s image of a honeybee coming into land. Brilliant stuff.

As it’s Saturday, I’m pointing you to the imaging and photography links page. Anyone on the course who wants to see some of my pre-course snaps from the recent Fen Edge Family Festival held in Cottenham in June they can check out my Imaging Storm website).

We are all made of stars

Stellar moleculesA cocktail of chemicals is venting in enormous jets from the oxygen-rich surroundings of a supergiant star 5000 light years from earth, according to Arizona radio astronomers. Using the the Arizona Radio Observatory’s 10m Submillimeter Telescope (SMT) on Mount Graham, which is so sensitive it could detect emissions from deep space that are weaker than a typical light bulb, the team has picked up the chemical signatures for a range of small molecules and ions.

Among the score of small chemical species detected in the environment around the supergiant star VY Canis Majoris is common salt (NaCl), hydrogen isocyanide, phosphorus nitride, and protonated carbon monoxide ions. These materials contain several of the elements critical to the formation of life, explain the researchers, something that was not expected to be found in the atmosphere of a cool dying star.

“I don’t think anyone would have predicted that VY Canis Majoris is a molecular factory. It was really unexpected,” says Arizona chemist Lucy Ziurys, Director of ARO, “Everyone thought that the interesting chemistry in gas clouds around old stars was happening in envelopes around much closer, carbon-rich stars.

We are all made of stars, but whether or not this latest evidence points to a stellar origin for life on earth remains to be seen. Apparently, comets and meteorites dump about 40,000 tonnes of interstellar dust on our planet each year, presumably this figure was much higher when the earth was mere millions of years old and given that most of its original carbon evaporated away from its primordial methane atmosphere it is very possible that we do indeed owe our existence to a heavenly body.

You can read my full write-up on this over on SpectroscopyNOW.com

Viscosity Corn Syrup Science Trick

Reverse laminar flow

I’m on a photography course this week, hence the leaner, meaner Sciencebase posting regime. But, I did find time to chat with technology writer Wayne Smallman on Blah Blah Tech, who pointed out this neat video showing three distinct coloured fluids (dyed corn syrup) being poured into a vessel stirred slowly and then the flow reversed.

You might suspect it is a trick, but it is not. The three coloured liquids end up separated but are not quite as perfectly aligned as they were at the start. Why does this happen? It’s laminar (non-mixing) reverse flow, is tied to the viscous nature of the corn syrup, the smooth flow of the mix and the reverse unmix. I guess the only trick might be that the three fluids are within a thin layer inside the cylinder within which is a second concentric cylinder, the stirrer, oh that and the fact that the “experimenter” cannot actually count! But the essential thing is that corn syrup has a low Reynolds number (this approximates to high viscosity).

Such effects do occur in nature at tidal river confluences where water from different flows barely mix because of differing temperatures and salt concentration. The same phenomena could underlie the seemingly stable patterns we see on Jupiter (it’s lots of viscous layers not mixing).

Anyway, here’s the video

As to what Wayne had to say about it. “Wow, well effin’ weird, or what?!” were his first words. He figured my “science know-how” would do it more justice. Well, personally, I think it’s just effin’ weird too! Seriously, for a more detailed explanation check out this page on the Harvard website. The video has also been discussed on StumbleUpon here.

Intellectual genetics

Tug of war

Two worthy legal moratoria – the Agreement on the Trade-Related Aspects of Intellectual Property Rights (TRIPS)
and the Convention on Biological Diversity (CBD) – are potentially in direct conflict when it comes to plant genetic resources and intellectual property rights, at least that is the conclusion of legal expert Megan Bowman. However, potential conflicts could be reconciled in this context by applying the common sense notion of remaining true to the over-arching principle of global welfare-maximisation in TRIPS and by utilising patent exemptions in appropriate circumstances. This, Bowman claims, will allow TRIPS and CBD to operate in a way that achieves both their objectives equally well so that intellectual property rights can be appropriately recognised and biodiversity can be sustained.

Writing in the International Journal of Intellectual Property Management (2007, Vol. 1, pp 277-292), who is a trained barrister and a lecturer in the Law School and Centre of Strategic Economic Studies, at Victoria University, Melbourne, Australia, points out that international recognition of intellectual property rights has grown, particular in the biotech arena, as biodiversity levels have fallen across the globe. Bowman points out that these two trends have become related since the creation of TRIPS and CBD in 1993 whose spheres of operation overlap significantly, particularly in relation to plant genetic resources and intellectual property rights. Bowman states that this is because biological diversity, at both genetic and physical levels, is being exploited as the key ingredient for lucrative biotech and pharmaceutical industrial creation. Patent protection of that creation raises questions about biodiversity sustainability and also access to the resultant benefits and technologies derived from use of a raw product ‘owned’ by source countries or communities.

Currently we are experiencing global biodiversity degradation and decimation due to causes such as global warming that may result in the extinction of nearly half the current lifeforms by 2050. Bowman comments: ‘Apart from the intrinsic value of biological diversity, without healthy and diverse ecological systems on this planet there is no quality of life for humans — no fresh air or water, no arable land or edible food, and exposure to devastating storms, floods and droughts. But at the same time, humans are evolutionary creatures and we see that clearly with technological innovation. We are also wed to the dollar and we see that, in the context of this discussion, in the jealous guarding of rent for patents, specifically in the growing sector of biotechnology and pharmaceuticals based on plant genetic resources. So the question is how do we marry these components in a way that honours each of them? I look at this question from a purely legal standpoint. Undoubtedly any solution is complex, multi-faceted and multi-disciplined. Nonetheless, the legal principles embedded in the key international treaties on protection of biodiversity and protection of intellectual property rights in plant genetic resources share a commitment to global welfare enhancement. So it becomes clear that the legal foundations exist for cooperation between these two sectors. This knowledge paves the way for productive dialogue and action in boardrooms, patent offices and parliaments around the world.’

Related article from the Sciencebase archives on corporate academia: Will publicly funded research become mired in patent protection and intellectual property rights or remain purely altruistic?

(Updated: August 21, 2007)

Mice and a slice

Raman brain sliceA new methodology for fibre-optic Raman mapping and FTIR imaging of secondary cancer cells, metastases, and detecting tumour cells has been developed by researchers in Germany. The technique facilitates imaging of samples thicker than 50 micrometres and could be used in detecting cancer cells, as a tool for molecular histopathology, in metabolic fingerprinting, general disease diagnostics.

Team member Christoph Krafft is currently in the Department of Materials and Natural Resources, at the University of Trieste, Italy, but will be returning to Dresden University of Technology with a new research grant in September. I spoke to him about the research and he told me that, “This fibre-optic Raman method will allow detecting tumour cells and tumour tissue in vivo and enable studies of tumor development.” You can read more details in the latest issue of SpectroscopyNOW.com in the Raman ezine.

Acronyms and abbreviations

Acronyms and abbreviations have always been a hobbyhorse of mine. Too many publications use them almost randomly without bothering to define. I suspect I’ve been guilty of that on occasion, but I try not to slip up. I was reading a thesis the other day that had so many acronyms and abbreviations without definition that I felt like failing the candidate there and then. Of course, I didn’t, it wasn’t my call.

If you’re looking for chemical and technical definitions then there are a couple of excellent acronym and abbreviation lookup services you can access, I’ll leave it to you to Google them…indeed, I think Google has a built in define acronym search logic.

Six degrees of privacy

Six dimensions of privacy

Worried about keeping your private details private on Facebook? Do you know what information Google stores on each and every search you do? What about your bank, do they track your online purchases and send that information to direct marketing agencies? These are all questions each and every one of us should know and want the answers to, but privacy issues are not clearcut. As more and more social interaction takes place on the Internet they have to be addressed. But, who, when, and how?

There is currently no common framework for communicating and discussing privacy issues, according to Nicholas Harkiolakis of the information technology department, Hellenic American University, in Greece. He hopes to change all that and has introduced the concept of an Information Privacy Unit (IPU). But, why should we worry about something so seemingly esoteric?

Well, Professor Harkiolakis has been involved in software development for a quarter of a century and has focused on applications in business and academic settings where issues of privacy are paramount. With the advent of the internet, we have seen an explosion in social interaction that crosses borders and allows people to communicate in ways that were undreamt perhaps as recently as when Harkiolakis began his career in IT. Social structure is changing from the level of the individual to corporations and to governments. “We have seen a major shift in power regarding control of personal data from the individual to public organisations and public bureaucracies,” Harkiolakis says.

He points out that companies that hold databases of personal information from our banks and clubs to internet service providers, websites and search engines are monitoring us all with very little regulation, and that is not taking into account the illicit monitoring of organisations of which we may not even be aware, such as those that infiltrate our computers with spyware and other nasties. “Other forms of monitoring could eventually be used to discriminate against individuals,” adds Harkiolakis, “not because of their past but because of statistical expectations about their future.” In particular, he says, we are simply unaware of what personal data has been captured and how it might be manipulated and used against us in some shape or form. If we, says Harkiolakis, we would never allow that data to be captured in the first place.

Writing in the International Journal of Technology Transfer and Commercialisation (2007, vol 6, 56-63) in a special issue on data protection, trust and technology, Harkiolakis explains the possible ways of addressing privacy concerns. He suggests that there six angles, or dimensions, to privacy that basically follow the journalistic mantra of What, When, Who, Where, Why and How. By taking this six-dimensional approach to privacy, Harkiolakis explains that it becomes possible to define strict guidelines for implementing privacy policies, specifically within software that will act as mediators (in web browsers, for instance) or as representatives (in other programs and on computer servers) between you, the user, and the proverbial them.

Cyberspace is vast, the amount personal information “out there” is enormous, just look at the rapidly growing number of web pages, ecommerce sites, Facebook and MySpace users, Diggers, bloggers and others. This growth has multiplied our abilities to manipulate and aggregate information beyond imagination, terabyte upon terabyte of data oscillates across the wires. Now that exchanging data across these wires, fibre optics, and satellite connections is entirely the norm and so privacy is a significant issue. The six-dimensional approach to privacy proposed by Harkiolakis looks at the manipulation of data from six different angles: Personal data (What) would have been collected with a variety of methods (How) by different entities (Who) at different times (When), at different websites or servers (Where) and for different purposes (Why). In a dispute, legal or otherwise, an investigation of each of these points in the transaction or use of data would allow both parties to examine whether any breaches of privacy, trust, or the law was made.

A breach at any of those six points would represent a breach however you look at it. Conversely, by developing software that can analyse and assess each of these individual dimensions and how they mesh together during a transaction it might one day be possible to produce a program, a browser plugin, for example, that monitors your activity on the Internet for you and warns you much more effectively than displaying a locked padlock in the status bar when a transaction is about to compromise your privacy.

Nicotine high hinges on sugar molecule

Nicotine structureWhen nicotine binds to a neuron, how does the cell know to send the signal that announces a smoker’s high? A recently determined crystal structure of a key player in the process suggests that a sugar molecule has a simple mechanical role acting as a hinge to open a gate in the cell membrane. The research might one day lead to new treatments for drug addiction, depression, epilepsy, schizophrenia, and other disorders.

I discussed the issue with Lin Chen of the University of Southern California and you can read the full story in the X-ray crystallography channel on SpectroscopyNOW.com