A former colonel in the FSB (the successor to the KGB) has allegedly fallen foul of chemistry. Alexander Litvinenko, 43, a vocal critic of Russian President Vladimir Putin, fell ill on November 1, after a meeting in a London sushi bar, reports the BBC.
Litvinenko is on life support in University College Hospital having allegedly been poisoned with a potentially lethal dose of the heavy metal thallium polonium. His condition is apparently serious but stable and he is under 24-hour armed surveillance. The BBC claims that his condition could be the work of the Russian Secret Service. Thallium (nor polonium) is certainly not available “over-the-counter” to the general public.
The alleged assassination attempt is revealed just as the British secret services try to exploit the marketing of the new James Bond movie – Casino Royale, starring Daniel Craig in the role of 007 – to recruit new spies. One British agent told BBC Radio 1 listeners that the secret services always work within the law and there is no license to kill. This thallium polonium attack comes in the wake of the gunning down in Moscow of journalist Anna Politkovskaya in October 2006 and perhaps does suggest that someone, somewhere does have a license to kill.
But, what exactly is thallium and why is it poisonous?
Thallium, Tl, is the element with atomic number 81 and lies just below indium in the periodic table (same column as boron, aluminium, and gallium). It’s tasteless, colourless, and odourless and would be undetectable if sprinkled into food or a drink in a restaurant.
Thallium ions have the same charge and are approximately the same size as potassium ions. As such, they can reach most tissues including the tissues of the central nervous system (CNS). Like other heavy metals, it binds to sulfydryl groups in the body disturbing numerous biochemical processes.
If you’re an ex-spy worried about meeting former colleagues in London sushi bars, you might be well advised to carry some D-penicillamine and Prussian blue with you. This combination can act as an effective antidote to thallium poisoning because these compounds have a greater affinity for the metal than the sulfhydryl compounds in your blood.
Canadian and Korean chemists have locked in a form of handedness into a common catalytic molecule that could make it useful for separating the building blocks of proteins, amino acids, into their chiral forms for biotech applications and drug development. The new locked up cat, might also be used to make purer and safer chemical starting materials for reactions in the drug, agrochemicals, and polymer industries.
New, healthier alternatives to processed food starches with a lower GI, or glycaemic index, may soon be on the menu, thanks to scientists in China and the US. The researcher have begun to unlock the secrets of starches that make dehusked grains, potatoes, and processed foods such as biscuits and breakfast cereals less healthy compared with low GI foods. Their statistical analysis of starchy data could lead to new processed carbohydrates that do not cause the worrying blood sugar spikes associated with conventional processed starch.
Arterial plaques represent a "death zone" within the artery in which white blood cells that would otherwise clear away such fatty deposits are killed before they can do their job.
A 25 femtosecond snapshot of a stick man is all that was needed to prove that a new free-electron laser technique would work. Unfortunately, the poor old stick man evaporated within that split second into a 60,000 degree plasma.
A natural analgesic (painkiller) that is six times stronger than the opiate