Fuel Cell Hydrogen Economy

Hydrogen fuel cells have been relatively neglected through insufficient support from industry and government, according to a study published today funded by the Economic and Social Research Council (ESRC).

‘Fuel cells are a genuine ‘clean’ technology,’ says study investigators, Chris Hendry of the Cass Business School, London, ‘But re-investment in nuclear technology is likely to squeeze out the investment necessary to make fuel cells competitive with existing energy sources and with other non-nuclear alternative energy options.’

I asked him about the true “cleanness” of fuel cells in the light of new infrastructure requirements, sourcing the requisite hydrogen and the recycling of equipment past its use by date.

“The ideal is to produce the hydrogen by electrolysis, using another renewable source,” he told Sciencebase, “Wind action in particular is intermittent – so when there’s too much generating electricity that can’t be used, it can be diverted to produce the hydrogen. Other countries can use solar for this purpose.”

But, what about sourcing that hydrogen before such technologies are fully viable?

“In the short-term, however, you’re right, the hydrogen will come from other hydrocarbons, particularly natural gas,” he adds, “This will enable fuel cells to become established using existing infrastructure, while a hydrogen infrastructure is developed.”

“In the end, the question is, which energy source has the most efficient
‘well-to-wheels’ costs, and which has also the least recycling costs?”

The study, co-written by Prof. Hendry, Dr. Paul Harborne, James Brown and Prof. Dinos Arcoumanis, gives a strong clue to one of the major obstacles to development by referring to fuel cell technology as a disruptive innovation. A disruptive innovation, if successful, eventually overturns the existing product on the market. Recent examples include the digital camera and the compact disc. Disruptive innovations are radically different from the existing dominant technology and to begin with they are often not as good. The result is two-fold. First the proponents of existing technology are likely to fear and so resist the new development. Second, because profits are unlikely to be immediate, funding can be problematic.

The automotive industry and stationary power provide examples of fuel cells as a disruptive innovation. However, while their potential is being pursued in the UK, Germany, North America and Japan, interviews with seventy companies in these countries show the UK fuel cell industry is lagging behind.

Jewelry Made with Molecules

Molecular jewelryPrecious jewelry is usually made with metals rather than molecules, although there is plenty of costume jewelry made with polymers and other materials which are of course composed of molecules. But, that’s not really a concern for madewithmolecules.com who are touting a chemically aware range of chokers, keychains, necklaces, charm bracelets, and even boxer shorts, sporting your favourite molecule.

So, for the chemist in your life, how about a serotonin necklace, or a pair of testosterone boxers, perhaps. A dopamine keychain tells the world you’re into love and pleasure (or that you’re on medication, perhaps) while acetylcholine earrings really show your neurones are firing on all four!

Then there are the estrogen items, for women who want to rejoice in their hormonal surges or for guys hoping to reveal their feminine side.

There are even glucose and oxytocin baby suits. Glucose being the key sugar molecule we all need right from birth and oxytocin being the feel-good hormone that completes the breast feeding cycle.

This post might look like an ad, but they didn’t pay me a dime for the privilege, I just had to tell sciencebase readers, many of whom are chemists.

Rust Never Sleeps

Rust never sleepsDumb materials succumb to rust, but smart materials might be able to heal themselves.

Researchers in Europe have devised a novel nano coating for metals and alloys that forms a very thin gel-like layer on the material. If this coating is damaged, the metal would normally be exposed to the elements. However, the nano particles contain a preservative that instead spreads to fill any microscopic cracks and holes that appear and quickly blocks them; preventing further attack from whatever corrosive agent was eating at the metal.

The current materials can heal cracks of up to 100 micrometres in size in water and in salt solutions. “The next stage is to develop the self-healing coatings to adapt them for other metals, such as steel,” Shchukin adds, “and to provide faster release of the inhibitor from the nanoreservoirs resulting in faster healing of the defects.”

Interview from the edge

In 2005, Andrew Lemon cofounded The Edge Software Consultancy, a multidisciplinary consulting company helping pharmaceutical and biotechnology companies to meet the challenges of modern drug discovery informatics. I interviewed him for the summer issue of the chemistry webzine Reactive Reports. “The complexity and diversity of experimentation during drug discovery and development only increases with time,” he told me, “Many areas are still not served with good software tools that help scientists to meet the challenges of changing dimensionality and uncertainty during the course of an experiment.” You can read the full interview, which is now live on the Reactive Reports site where you’ll find out how Lemon’s company can provide a solution for data management to make it accessible. “Learning from every piece of data collected and then applying that knowledge across the whole process is going to be the key challenge,” he added.

Read on…

Recycling Plastics Sorted

recycling plasticPlastic waste is a mess. Disposal in landfill is the worst option but recycling post-consumer plastic waste presents a technological nightmare given the huge range of polymers used in packaging and products. A rapid, online method of identifying the different plastics in a recycling stream would provide a way to sort them and allow recycling plants to operate far more efficiently and perhaps make plastic recycling commercially viable.

A technique being investigated by Spanish researchers to this end is laser-induced plasma spectroscopy (LIPS). Jesús Anzano, María-Esther Casanova, María-Soledad Bermúdez, and Roberto-Jesús Lasheras of the Laser Analytical Spectroscopy Lab at the University of Zaragoza, in Spain, have now demonstrated that LIPS used in conjunction with a simple statistical correlation method can indeed differentiate between plastics prior to recycling.

Recycle the full story here

Molecular Photos

Hexaferrocenylbenzene structureWill Davis emailed me from France to ask if the molecular structures on the site are photos:

“I have read a book written about five years ago by a research biologist who wrote that …no one has seen a molecule. Now I see on your website photos of molecules. Are these real photos or a representation. Is this biologist either wrong or out of date?”

Well, he’s right and he’s wrong. You cannot take a photograph of a molecule. For a photograph you need light and the wavelength of visible light is just toooo long to resolve the features of a molecule. So, no, those aren’t photos of molecules you see littered around Sciencebase, I draw them using software such as ACD/Labs’ ChemSketch and then render them in Diamond, which can produce photorealistic renditions of a chemical structure. An additional step to add shadowing and make them even more 3D realistic is possible using Pov-Ray.

However, that said, molecular imaging has moved on during the last few years and it is possible to detect the presence of a molecule using the tip of something like an atomic force microscope (AFM) and to then use the perturbations of the tip to generate a three-dimensional image of the surface of said molecule.

Copper Sulfate Swimming Pool

swimming poolBelgian scientists today reiterated a warning that certain cases of asthma could be linked to swimming in stuffy “chlorinated” indoor pools but chemistry may have the answer, according to charity Allergy UK, which has awarded its ‘Seal of Approval’ to a novel alternative of which hot-tubbing ancient Greek philosopher Archimedes would be proud.

The novel solution involves using copper sulfate at levels permitted for drinking water to temper bacterial blooms in a swimming pool rather than to attempt to destroy them completely. The idea was discovered by the Greeks way back when but is used today by NASA to keep drinking water clean in space.

The product, which goes by the name Pristine Blue, is approved for use in the US, and allows the 1 in 3 kids who suffer an allergic reaction to pool “chlorine” to get in the swim without having to worry about the reaction. It also means an end to stinging eyes, which are caused by pool “chlorine” reacting with nitrogen compounds in sweat and urea that mysteriously make their way into most pools.

The copper sulfate approach also avoids damage to hair, swimming costumes, and pool liners, which normally suffer from the bleaching effects of chlorine.

Allergy UK’s Business Development Director, Jules Payne, said Pristine Blue could transform the lives of millions of families across the UK. ‘We are very excited to present this award to such a groundbreaking and innovative product,” she said, “The benefits to allergy suffers are immense, and as families prepare for their summer holidays the demand for a chlorine alternative is at its highest.”

Red Red Wine

red red wine

An ideal solution for accurately and rapidly monitoring red, red wine during the fermentation process without the need for direct sampling for chemical analysis has been developed by Australian researchers led by Daniel Cozzolino of the Australian Wine Research Institute, in Adelaide.
The team recognised the need of the modern wine industry for tools that can assist in process control and quality assessment during fermentation and bottling but that can be carried out without complex sampling, preparation by an external lab. they have used chemometrics and Visible-near infrared spectroscopy to monitor concentrations of sugars and phenolic compounds, in red wine and so offer the industry a new approach to quality control.

Uncork vintage news here.

Face to face with gold nanoparticles

gold nanoparticles

Bling comes to the world of nanotechnology, as japanese scientists coat crystals with gold particles. The modification of specific crystal faces of organic single crystals using gold nanoparticles could open up new possibilities for crystal engineering of materials with novel optical, electronic, and catalytic properties, according to the researchers.

Kazuki Sada, Seiji Shinkai, and colleagues of Kyushu University, in Fukuoka, Japan, have demonstrated that gold nanoparticles can be made to adhere to only certain faces of crystals of the amino acid cystine, suggesting that such “building blocks” might be used for creating sophisticated nanostructures with designer facets.

Read about the ultimate nano bling here.

Dietary stress

fat rat

“Diet is an important part of healthy living,” Jeremy Nicholson of Imperial College revealed to SpectroscopyNOW, “it is just some things that are supposed to relieve stress – and widely touted by healthfood companies as being good for you – do not metabolically ameliorate the effects of even very minor experimental stress.” He and his colleagues have used NMR spectroscopy to analyse marker compounds in blood samples from rats under stress that have had their food switched to included polyunsaturated fats. “No one has actually tested this particular health claim before and this one doesnt stand up well,” Nicholson says. Additionally, the research shows it is possible to accurately measure and quantify how changing diet impacts health. This could ultimately lead to the development of more targeted and more effective products.

You can read the full details in my news round-up on spectroscopynow.com